"Tectosilicates": Framework silicates - SiO2
Si:O ratio is 1 : 2
The tectosilicate group includes the most abundant minerals composing the Earth's crust.
These include:
Orthoclase Feldspar - 12%
Quartz - 12%
SiO2 Group
Feldspar Group - (SiO2)4 = Si4O8
- Al+3 substitutes for 1 - 2 Si+4
to balance the charge difference and allow the addition of other cations
For example:
Click here for a triangular compositional diagram of the feldspars
http://classes.colgate.edu/rapril/geol201/
Examples of Tectosilicates:
Tetrahedra share all 4 oxygens with neighboring tetrahedra:
Plagioclase Feldspar - 39%
Quartz - SiO2
Orthoclase KAlSi3O8
Albite NaAlSi3O8
Labradorite (Ca,Na)(Al,Si)4O8
Anorthite CaAl2Si2O8
2 Polymorphs of Quartz:
Low Quartz (low pressure/low temp. conditions)- Hex/rhomb system
High Quartz (low pressure/high temp. conditions) - hex/hex system
One method that the SiO2 structure changes from one polymorph to another is
by:
Tridymite
High Tridymite - hex.hex system
Cristobalite
Low Tridymite - orthorhombic system
High Cristobalite - isometric system
Coesite
Low Cristobalite - tetragonal system
Stishovite
Stability Fields for the SiO2 Group
Reconstructive Transformation
- this involves the breaking and reforming of bonds
- the process is slow (may take a million years) and irreversible
K+1AlSi3O8
Ca+2Al2Si2O8
Back to Main Silicate Page
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