General Formula: W0-1X2Y5Z8O22(OH, F, Cl)2
W: 10-12 fold site (A1 site) -
Na+, Ca2+ - coordination with OH- in some cases
X: 6-8 fold site (M4 site)
Ca2+, Na+, Mn2+, Fe2+, Mg2+,
Li+
Y: 6 fold site (M1, M2, M3 possibilites) -
Mg2+, Fe2+, Fe3+, Al3+, Ti4+
(only Ca can't fit here)
Z: typical tetrahedral - 4-fold site -
usually Si42+, Al3+ - rarely anything else
http://classes.colgate.edu/rapril/geol201/ |