Mineralogy
Crystallography
Crystallography: The internal arrangement of atoms in crystals and how this is reflected by its external morphology

Unit Cell: The smallest unit of a crystal that still retains all the physical, chemical and crystallographic properties of the mineral.



Symmetry operations: Movements performed on an object such that when completed, the object looks the same as when you started.

The 4 pure symmetry operations (which are operations that leave one point in the crystal unmoved) include:

  1. Rotation Axis - An axis through the object, around which the object is rotated such that the original "motif"
                                  (or appearance) is repeated a specific number of times during 360 degrees

      Fold of
      Rotation
      1
      2
      3
      4
      6
      Shorthand
      Notation
       
      1A2
      1A3
      1A4
      1A6
      Stereonet
      Symbol
       
      football
      triangle
      square
      hexagon
      Amount of Rotation
      Needed to Repeat Image
      360°
      180°
      120°
      90°
      60°


  2. Mirror plane: plane passed through object such that the images on opposite sides of the plane
                                are mirror images of one another

      Shorthand Notation
      1m
      Stereonet Symbols
      vertical mirror
      solid line
      horizontal mirror
      solid primitive circle
      tilted mirror
      solid great circle line

  3. Roto-inversion axis: first a rotation (the amount of this rotation determines the fold of the axis),
                                then an 180° inversion around the center point of the crystal

      Shorthand Notation
      (x=fold of rotation)

      Stereonet Symbol

  4. Center of symmetry : is present if two lines of equal length can be extended from the center of a
                                crystal in opposite directions, and reach equivalent elements on the crystal's surface.

      Shorthand Notation
      i
      Stereonet Symbol
      none



    There are 32 possible combinations of the 4 pure symmetry elements that exist in nature.
    These make up the 32 Crystal Classes.
    Crystal classes are grouped into 6 Crystal Systems based on shared symmetry.

    Crystal systems:

      System Name Shared Symmetry Axial Lengths Angles
      Triclinic i or none a ≠ b ≠ c α ≠ β ≠ γ   no angle = 90°
      Monoclinic 1A2 and/or 1m a ≠ b ≠ c β ≠ α = γ = 90°
      Orthorhombic 3A2 and/or 1A22m a ≠ b ≠ c α = β = γ = 90°
      Tetragonal 1A4 a1 = a2 ≠ c α = β = γ = 90°
      Hexagonal hex/hex:1A6
      a1 = a2 = a3 ≠ c β1 = β2 = β3 = 90°
      γ1 = γ2 = γ3 = 120°
      hex/rhomb:1A3
      a1 = a2 = a3 = c
      Isometric 4A3 a = b = c α = β = γ = 90°




    * Note: Most minerals form in the classes with the highest symmetry in each system.
      These are called "holohedral classes or holosymetric" classes.

    The holohedral classes for each system are:



    5 Planar Nets (2-dimensional atomic arrangements)

      Oblique  oblique t1 < t2 Rectangular  rectangulart1 < t2
      Square squaret1 = t2 Rhombic rhombic/hexagonalt1 = t2
      Centered Rectangulardiamond is formed by connecting the shared corners & centers
                                                                  of two adjacent rectangles. i.e., diamond



    14 Bravais Lattices (3-dimensional atomic arrangements)

    Formed by extending planar nets into 3rd dimension. Atom positions within Bravais Lattices can occur as follows:




    Steno's Law of the Constancy of Interfacial Angles: The angles between equivalent faces of crystals of the same substance, measured at the same temperature, are consistently the same.

    Zone: Faces of a crystal that intercept such that their edges run parallel to each other make up a "zone."

    Form: Faces that share the same relationship to the symmetry that is present in a crystal are grouped together as a "form."


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