Mineralogy
Crystallography

Crystallography: The internal arrangement of atoms in crystals and how this is reflected by its external morphology

Unit Cell: The smallest unit of a crystal that still retains all the physical, chemical and crystallographic properties of the mineral.

Symmetry operations: Movements performed on an object such that when completed, the object looks the same as when you started.

The 4 pure symmetry operations (which leave one point in the crystal unmoved) include:

  1. Rotation Axis - An axis through the object, around which the object is rotated such that the original "motif" (or appearance) is repeated a specific number of times during 360 degrees

    Fold of
    Rotation
    1
    2
    3
    4
    6
    Shorthand
    Notation
     
    1A2
    1A3
    1A4
    1A6
    Stereonet
    Symbol
     
    football
    triangle
    square
    square
    Degrees to
    Repeat Image
    360
    180
    120
    90
    60

  2. Mirror plane: plane passed through object such that the images on opposite sides of the plane

    Shorthand Notation
    1m
    Stereonet Symbol
    lines and primitive circle

  3. Roto-inversion axis: first a rotation, then an inversion of 180 degrees

    Shorthand Notation

    Stereonet Symbol

  4. Center of symmetry : if a line is extended from the center of an object a certain length in a certain direction, and another line of equal length but in the opposite direction, equivalent elements exist at both points.

    Shorthand Notation
    i
    Stereonet Symbol
    none



There are 32 possible combinations of the 4 pure symmetry elements that exist in nature. These make up the 32crystal classes. Crystal classes are grouped into 6 crystal systems based on shared symmetry.

Crystal systems:

System Name
Shared Symmetry
Axial Lengths
Angles
triclinic
i or none
monoclinic
1A2 and/or 1m
orthorhombic
3A2 and/or 1A22m
tetragonal
1A4
football
hexagonal
hex:1A6
rhomb:1A3
hex:
rhomb:
isometric
4A3

*note: largest number of mineral species is concentrated in the crystal class with the highest symmetry of each system. These classes with the highest symmetry in each system are called "holohedral classes". They include:


5 planar nets (2-dimensional atomic arrangements)

Oblique  oblique t1 < t2 Rectangular  rectangulart1 < t2
Square squaret1 = t2 Rhombic rhombic/hexagonalt1 = t2
Centered rectangulardiamond is formed by

14 Bravais Lattices (3-dimensional atomic arrangements)

Formed by extending planar nets into 3rd dimension. Atom positions within Bravais Lattices can occur as follows:


Law of Constancy of Interfacial Angles: regardless of deformation during formation, all angles between faces will be perfect

Zone: if the faces of a crystal intercept to form edges and those edges are parallel - they form a zone


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